Synthesis and Characterization of Donor-Functionalized N,S-Compounds Containing the ortho-Aminothiophenol Motif

Date

2011, 2011, 2011

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Abstract

A series of twenty S-benzyl ortho-aminothiophenol and S,S'-xylylene-bridged bis(ortho-aminothiophenol) compounds and their imine derivatives have been synthesized in moderate to excellent yields and characterized. The syntheses were optimized, including large-scale syntheses, and an improved purification method involving the HCl salt was developed. This paper also serves as a comprehensive review of xylylene-bridged bis(ortho-aminothiophenol) compounds.

Description

Keywords

complexes, coordination, ligands, 2-aminothiophenol, alkylation, electronic-structures, excited-state, ionophore character, nitrogen, noninnocence, rearrangements, regioselective mercuration, Schiff bases, sulfur, School of Science and Technology

Citation

URI

https://hdl.handle.net/20.500.14639/607

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